化学化工学院
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校友风采  
舒兴中
发布时间:2015-09-24    点击:[]

舒兴中,男,理学博士,兰州大学“萃英学者”特聘教授,博士生导师。1982年生于浙江衢州,2005年毕业于绍兴文理学院。于2005-2010年在兰州大学攻读博士学位,从事药物小分子骨架高效合成方法学研究,师从梁永民教授。于2010-2012年在威斯康辛大学麦迪逊分校(University of Wisconsin-Madison)从事博士后研究,开发新型Rh催化[5+2]环加成反应,师从Weiping Tang教授。于2012-2015年,在加州大学伯克利分校(University of California Berkeley)和劳伦斯伯克利国家实验室(Lawrence Berkeley National Laboratory)从事博士后研究,探索新能源、新材料与有机化学学科的交叉研究,师从著名有机化学家F. Dean Toste教授和材料学家Paul Alivisatos教授(劳伦斯伯克利国家实验室主任,美国科学院院士);合作导师:光化学家Heinz Frei教授和“表面催化之父”Gabor Somorjai院士)。于2015年起在兰州大学化学化工学院、功能有机分子化学国家重点实验室从事教学科研工作。

研究以能源、环保、医药等行业为向导,开发高性能均相、多相金属催化剂,开展(不对称)催化和反应机理研究。主要包括:1)新型廉价金属催化剂的设计、制备和催化活性研究,用于解决合成反应中传统方法难以实现的化学转化和反应选择性问题;2)整合过渡金属催化与新型材料技术,开发高性能纳米金属有机材料催化剂;3)探索过渡金属(均相/多相)催化参与的人工光合作用研究。迄今为止,已在Chem. Soc. Rev.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed. 、NanoLett.等国际著名刊物上发表论文三十余篇,他引800余次, H因子19。成果被Synfacts、Organic Chemistry Portal等多家专业媒体报道。曾获2009年中国青少年科技创新奖、2009年中国科学院奖学金、2008年宝钢教育奖学金、2005年浙江省优秀毕业生等。是多家国际一流期刊的应邀审稿人,美国化学会会员。

近期代表性论文:

[15] Xing-zhong Shu, Miao Zhang, Ying He, Heinz, Frei*, F. Dean Toste*, “Dual Visible Light Photoredox and Gold-catalyzed ArylativeRing Expansion”, J. Am. Chem. Soc. 2014, 136, 5844.

[14] Elad Gross, Xing-Zhong Shu, SelimAlayoglu, Hans A. Bechtel, Michael C. Martin, F. Dean Toste,* Gabor A. Somorjai*, “In situ IR and X‑ray High Spatial-resolution MicrospectroscopyMeasurements of Multistep Organic Transformation in Flow MicroreactorCatalyzed by Au Nanoclusters”, J. Am. Chem. Soc., 2014, 136, 3624.

[13] Qiao Zhang, Xing-Zhong Shu, J. Matthew Lucas,F. Dean Toste*, Gabor A. Somorjai*, A. Paul Alivisatos*, “Inorganic Micelle as an Efficient and Recyclable Micellar Catalyst”, NanoLett. 2014,14, 379.

[12] Xing-zhong Shu, Casi M. Schienebeck, Wangze Song, Ilia A. Guzei, and Weiping Tang*, “Transfer of Chirality in Rhodium-Catalyzed Intramolecular (5+2) Cycloaddition of 3-Acyloxy-1,4-enyne (ACE) and Alkyne: Enantioselective Synthesis of Bicyclo[5.3.0]decatrienes”, Angew. Chem. Int. Ed.2013, 52, 13601.

[11] Xiufang Xu*, Peng Liu, Xing-Zhong Shu; Weiping Tang*; Houk, K. N.*, “Rh-Catalyzed (5+2) Cycloadditions of 3-Acyloxy-1,4-enynes and Alkynes: Computational Study of Mechanism, Reactivity, and Regioselectivity”, J. Am. Chem. Soc., 2013, 135, 9271.

[10] Xing-Zhong Shu, Dongxu Shu, Casi M. Schienebeck and Weiping Tang*, “Rhodium-catalyzed AcyloxyMigration of PropargylicEsters in Cycloadditions, Inspiration from the Recent "Gold Rush"”, Chem. Soc. Rev.2012, 41, 7698.

[9] Xing-Zhong Shu, Xiaoxun Li, Dongxu Shu, Suyu Huang, Casi Mae Schienebeck, Xin Zhou, Patrick J. Robichaux, Weiping Tang, “Rhodium-Catalyzed Intra- and Intermolecular 5+2 Cycloaddition of 3-Acyloxy-1,4-enyne and Alkyne with Concomitant 1,2-Acyloxy Migration”, J. Am. Chem. Soc., 2012, 134, 5211.

[8] Xing-Zhong Shu, Suyu Huang, Dongxu Shu, Ilia A. Guzei, Weiping Tang*, “Interception of a Rautenstrauch Intermediate by Alkynes for 5+2 Cycloaddition: Rhodium-Catalyzed Cycloisomerization of 3-Acyloxy-4-ene-1,9-diynes to Bicyclo 5.3.0 decatrienes”, Angew. Chem. Int. Ed.2011, 50, 8153.

[7] Xing-Zhong Shu, Yan-Fang Yang, Xiao-Feng Xia, Ke-Gong Ji, Xue-Yuan Liu, Yong-Min Liang*, “Platinum-catalyzed Cross-dehydrogenativeCoupling Reaction in the Absence of Oxidant”, Org. Biomol. Chem.2010, 8, 4077.

[6] Xing-Zhong Shu, Xiao-Feng Xia, Yan-Fang Yang, Ke-Gong Ji, Xue-Yuan Liu, Yong-Min Liang*, “Selective Functionalization of Sp(3) C-H Bonds Adjacent to Nitrogen Using (Diacetoxyiodo)benzene (DIB)”, J. Org. Chem. 2009, 74, 7464.

[5] Xing-Zhong Shu, Shu-Chun Zhao, Ke-Gong Ji, Zhao-Jing Zheng, Xue-Yuan Liu, Yong-Min Liang*, “Platinum-Catalyzed Cyclization of o-Alkynyl(oxo)benzenes with Alkenes by 1,2-Migration of Benzene: Synthesis of 8-Oxabicyclo 3.2.1 octane Derivatives”, Eur. J. Org. Chem. 2009, 117.

[4] Xing-Zhong Shu, Ke-Gong Ji, Shu-Chun Zhao, Zhao-Jing Zheng, Jing Chen, Li Lu, Xue-Yuan Liu, Yong-Min Liang*, “Synthesis of Naphthalenyl Acetate by Platinum-Catalyzed 1,5-Sigmatropic Hydrogen Shift of Propargylic Esters”, Chem. Eur. J. 2008, 14, 10556.

[3]Xing-Zhong Shu, Xue-Yuan Liu, Ke-Gong Ji, Hui-Quan Xiao, Yong-Min Liang*, “Au-catalyzed Tandem Cyclization/1,2 -alkyl Migration Reaction of Epoxy Alkynes: Synthesis of Spiropyranones”, Chem. Eur. J.2008, 14, 5282.

[2] Xing-Zhong Shu, Xue-Yuan Liu, Hui-Quan Xiao, Ke-Gong Ji, Li-Na Guo, Yong-Min Liang*, “Tandem Gold(III)-catalyzed Amination-intramolecular HydroaminationReactions of 1-En-4-yn-3-ols with Sulfonamides: Efficient Approach to Highly Substituted Pyrroles”, Adv. Synth. Catal. 2008, 350, 243.

[1] Xing-Zhong Shu, Xue-Yuan Liu, Hui-Quan Xiao, Ke-Gong Ji, Li-Na Guo, Chen-Ze Qi, Yong-Min Liang*, “Gold-catalyzed Tandem Cycloisomerization of Alkynyloxiranes with Nucleophiles: An Efficient Approach to 2,5-Disubstituted Furans”, Adv. Synth. Catal. 2007, 349, 2493.


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