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材料化学与工程系

材料化学与工程系简介
2020-10-19 08:19  

   本学科开展基础研究与应用研究的主要领域有:

1.物理有机化学精细化学品合成工艺新技术药物合成绿色化学

2.多相催化及催化材料介孔和纳米结构材料能源化学工程

3.高分子合成高分子的结构与性能关系;功能高分子材料生物与药材料等。

浙江省精细化学品传统工艺替代技术研究重点实验室2014-2016年间的绩效评价考核优秀。2015以来,在一批国家浙江省科技项目的支持下,在化学、材料科学与工程、化学工程等领域的国际学术杂志发表了一系列创新性的研究成果。

l国家自然科学基金项目

1.齐陈泽正电子在过渡金属催化剂中的湮没行为与催化剂活性的关联关系项目120751542021-2024.

2.何冰基于酸掺杂聚苯胺修饰石墨烯的酸性氧还原性能研究项目号220051922021-2023.  

3.董坚,天然气水合物动力学抑制剂的结构与性能关系研究项目号219730612020-2023.

4.高勇,杂壳结构ABC三嵌段共聚物胶体粒子稳定的非水Pickering乳液(项目号219712202020-2023.

5.杨鹏,铌基复合氧化物的可控合成及其对含氯有机污染物催化燃烧性能研究(项目号219062162020-2022.  

6. 曾敏峰,用正电子湮没谱学研究无机柱撑/大分子插层协同改性蒙脱土负载钯催化材料的缺陷结构及其对催化性能的影响(项目号118751932019-2022.

7. 郦勇,Stemmadenine类型生物碱及其生源衍生天然产物Arborisidine的不对称合成研究项目号218011672019-2021.

8. 李琰,从促氧化与抗耐药的双重角度研究荜茇酰胺类似物的抗癌活性及作用机制项目号318002922019-2021.  

9. 邵林军/壳聚糖纳米纤维的微观结构与催化性能关联性研究(项目号117051172018-2020.

10. 冯高峰新型分散染料多样性导向绿色合成及结构与性能研究项目号216761662017-2020.

11.  董坚新型两亲性天然气水合物动力学抑制剂的合成与作用机理研究(项目号216740632017-2018.

12. 齐陈泽有序介孔高分子功能材料微观结构的正电子湮没研究 (项目号11575117)2016-2019.

13. 左树锋功能化无机复合柱撑粘土吸附-脱附-催化燃烧VOCs性能与机理研究 项目号215770942016-2019.

14. 曾敏峰,聚合物负载过渡金属非均相催化材料的微观结构与催化性能的关联关系研究项目号114751142015-2018.

15. 程凯,银催化的通过C-H官能化构筑C-C/C-N键的反应研究项目号21402123 2015-2017.

l化学领域发表的代表性论文:

1.  齐陈泽, Efficient biomass transformations catalyzed by graphene-like nanoporous carbons functionalized with strong acid ionic liquids and sulfonic groups.Green Chemistry 2015.  

2. 邵林军, 齐陈泽 等, Developing chitosan-based composite nanofibers for supporting metal catalysts. Polymer, 2015.

3.王晨,Mechanistic Study on Gold-Catalyzed Highly Selective Hydroamination of Alkylidenecyclopropanes. Journal of Organic Chemistry2016.

4. 齐陈泽,Template-free synthesis of porous carbonaceous solid acids with controllable acid sites and their excellent activity for catalyzing the synthesis of biofuels and fine chemicals. Catalysis Science & Technology 2016.

5. 齐陈泽,Ordered Mesoporous Polymers for Biomass Conversions and Cross-Coupling Reactions. ChemSusChem 2016.  

6.冯若昆.Selective Synthesis of Alkynylated Isoquinolines and Biisoquinolines via RhIII Catalyzed C-H Activation/1,3-Diyne Strategy. Journal of Organic Chemistry 2017.

7. 程凯. Acid-promoted denitrogenative Pd-catalyzed addition of arylhydrazines with nitriles at room temperature. Organic Chemistry Frontiers 2017.

8. 王晨. Mechanism and Origin of Chemical Selectivity in Oxaziridine-Based Methionine Modification: A Computational Study. Journal of Organic Chemistry 2017.

9. 杨鹏. Promoting effects of Ce and Pt addition on the destructive performances of V2O5/γ-Al2O3 for catalytic combustion of benzene. Applied Catalysis A-General 2017.

10. 董坚. Studies of Relationship between Polymer Structure and Hydration Environment in Amphiphilic Polytartaramides. Journal of Polymer Science. Part B– Polymer Physics 2017.

11.杨鹏.Promoting oxidative activity and stability of CeO2 addition on the MnOx modified kaolin-based catalysts for catalytic combustion of benzene.Chemical Engineering Science 2017.    

12.冯高峰, Carbamoyl Radicals via Photoredox Decarboxylation of Oxamic Acids in Aqueous Media: Access to 3,4-Dihydroquinolin-2(1H)-ones. Organic Letters 2018.    

13. 程凯,齐陈泽, Silver-catalyzed double decarboxylative radical alkynylation/ annulation of arylpropiolic acids with α-keto acids: access to ynones and flavones under mild conditions. Advanced Synthesis & Catalysis 2018.

14. 程凯,齐陈泽, Pd(II)-catalyzed Denitrogenative & Desulfinative Addition of Arylsulfonyl Hydrazides with Nitriles. Journal of Organic Chemistry 2018.

15. 冯若昆齐陈泽, One-pot Synthesis of Alkynylated Coumarins via Rhodium-Catalyzed Annulation of Aryl Thiocarbamates with 1,3-Diynes or Terminal Alkynes.Advanced Synthesis & Catalysis 2018.  

16.  张富仁, Solid acid-catalyzed domino cyclization reaction: regio- and diastereoselective synthesis of pyrido[2,3-d]pyrimidine derivatives bearing three contiguous stereocenters.Green Chemistry 2018.

17.  董坚, Amphiphilic Optimization Enables Polyaspartamides with Effective Kinetic Inhibition of Tetrahydrofuran Hydrate Formation: Structure–Property Relationships.

ACS Sustainable Chemistry & Engineering 2018.

18.杨鹏,左树锋,齐陈泽, Synthesis of Nb2O5 based solid superacid materials for catalytic combustion of chlorinated VOCs. Applied Catalysis - B: Environmental 2018.    

19.董坚等,Hydrophobic hydration affects growth of clathrate hydrate: insight from NMR relaxometric and calorimetric study. Chemical Communications 2019.    

20. 程凯 等,Visible Light-Catalyzed Decarboxylative Alkynylation of Arenediazonium Salts with Alkynyl Carboxylic Acids: Direct Access to Aryl Alkynes by Organic Photoredox Catalysis. Advanced Synthesis & Catalysis 2019.

21. 张富仁, A multicomponent two-step strategy for the synthesis of polysubstituted

pyrrolo[3, 2-c] pyridin-4-ones using a solid acid as a recyclable catalyst. Green Chemistry 2019.

22. 高勇 等,Triple-Responsive Pickering Emulsion Stabilized by Core Cross-linked    

Supramolecular Polymer Particles. Langmuir2019.    

23.齐陈泽等,Developing two-dimensional solid superacids with enhanced mass transport,

extremely high acid strength and superior catalytic performance. Chemical Science  2019.

24.何冰, Development of g-C3N4 activated hollow carbon spheres with good performance

for oxygen reduction and selective capture of acid gases. Electrochimica Acta, 2019.

25.王晨  . Cobalt/Lewis Acid Catalysis for Hydrocarbofunctionalization of Alkynes via

Cooperative C-H Activation. Journal of the American Chemical Society 2020.

26.董坚. Polymer hydrogel confined palladium nanoparticles as recyclable catalysts for

Suzuki and Heck cross-coupling reactions. Chinese Chemical Letters 2020.

l材料科学、化学工程等领域发表的代表性论文

1.何冰, 齐陈泽 等, Synthesis of nitrogen-doped monolayer graphene with high transparent and n-type electrical properties. Journal of Materials Chemistry C 2015.  

2.左树锋, 齐陈泽 等Study on the preparation and characterization of a titanium-pillared clay-supported CrCe catalyst and its application to the degradation of a low concentration of chlorobenzene. Applied Clay Science2015.

3. 左树锋, 齐陈泽 等,Preparation and characterization of novel composite AlCr-pillared clays and preliminary investigation for benzene adsorption,Applied Clay Science, 2015.

4. 曾敏峰,Encaging Palladium Nanoparticles in Chitosan Modified Montmorillonite for Efficient, Recyclable Catalysts. ACS Applied Materials & Interface2016.

5. 曾敏峰,N-doped mesoporous carbons supported palladium catalystsprepared from chitosan/silica/palladium gel beads.International Journal of Biological Macromolecules2016.

6. 冯高峰, Synthesis, Characterization, and Application of Diester/diurethane Tethered Azo Disperse Dyes: A New Strategy to Improve Dye’s Fastness Properties. Dyes and Pigments 2016.

7. 董坚,Robust nickel-polymer nanocomposite particles for hydrogen generation from sodium borohydride. Fuel 2016.

8.董坚,Ni-polymer nanogel hybrid particles: a new strategy for hydrogen production from the hydrolysis of dimethylamine-borane and sodium borohydride. Energy, 2016.

9.梁学正, Magnetic solid acid catalyst for biodiesel synthesis from waste oil. Energy Conversion & Management 2017.

10.何冰, Temperature-directed growth of highly pyridinic nitrogen doped, graphitized, ultra-hollow carbon frameworks as an efficient electrocatalyst for the oxygen reduction reaction. Journal of Materials Chemistry A 2017.

11. 左树锋,Study of CeO2 Modified AlNi Mixed Pillared Clays Supported Palladium Catalysts for Benzene Adsorption/Desorption-Catalytic Combustion. Materials 2017.  

12. 曾敏峰,Co-immobilization of Pd and Zn nanoparticles in chitosan/silica membranes for efficient, recyclable catalysts used in Ullmann reaction. International Journal of Biological Macromolecules 2017.

13. 董坚,Poly(glucono-δ-lactone) based nanocarriers as novel biodegradable drug delivery platforms. International Journal of Pharmaceutics 2017.

14. 杨鹏,左树锋,齐陈泽, Adsorption/catalytic combustion of toxic 1,2-dichloroethane on multifunctional Nb2O5-TiO2 composite metal oxides. Chemical Engineering Journal 2018.

15. 杨鹏 等 Synthesis of W-Nb-O solid acid for catalytic combustion of low-concentration monochlorobenzene. Chemical Engineering Journal 2019.

16. 蒋谞,苟发亮,齐陈泽,C2v-symmetric metalloporphyrin promoted cycloaddition of epoxides with CO2 under atmospheric pressure. Journal of CO2 Utilization 2019.

17.  曾敏峰 等 Modification of Montmorillonite with Polyethylene Oxide and Its Use as Support for Pd0 Nanoparticle Catalysts. Polymers 2019.

18.  邵林军 等 Cobalt, copper and nickel-embedded chitosan/PAAS composite nanofiber mats as efficient heterogeneous catalysts for air oxidation of benzoin to benzil, Cellulose, 2019.

19.  左树锋, Ce-modified mesoporous γ-Al2O3 supported Pd-Pt nanoparticle catalysts and their structure-function relationship in complete benzene oxidation. Chemical Engineering Journal2019.  

20. 左树锋, Rare earth modified kaolin-based Cr2O3 catalysts for catalytic combustion of chlorobenzene. Applied Catalysis A - General  2019.  

21. 齐陈泽 ,Effects of the π-electrons in fused polycyclic aromatic hydrocarbons on positron annihilation. Radiation Physics and Chemistry  2019.

22.  冯高峰 等,Diversity-oriented synthesis of azo disperse dyes with improved fastness properties via employing Ugi four-component reaction. Dyes and Pigments, 2019.

23.  左树锋 等, La2O3 modified silica-pillared clays supported PtOx nanocrystalline catalysts for catalytic combustion of benzene. Chemical Engineering Journal. 2020.

24.  曾敏峰 等, Preparation of porous chitosan/reduced graphene oxide microspheres supported Pd nanoparticles catalysts for Heck coupling reactions. Carbohydrate Polymers 2020.

25. 董坚  等, Controlling water dynamics for kinetic inhibition of clathrate hydrate. Fuel 2020.

26. 马德琨 等, Cu nanowire bridged Bi nanosheet arrays for efficient electrochemical CO2 reduction toward formate. Journal of Alloys and Compounds  2020.

27. 曾敏峰 等,Chitosan modified Ti-PILC supported PdOx catalysts for coupling reactions of aryl halides with terminal alkynes. International Journal of Biological Macromolecules 2020.

28. 董坚 等,Dependence of Kinetic Hydrate Inhibition Effect of Poly(N-vinyl pyrrolidone) upon Molecular Weight Is Influenced by Water Mobility in Millisecond Dynamics.

   Energy & Fuels 2020.      

   

   

 

   

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